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Muconolactone Delta-isomerase
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Muconolactone Delta-isomerase : ウィキペディア英語版
Muconolactone Delta-isomerase

In enzymology, a muconolactone Delta-isomerase () is an enzyme that catalyzes the chemical reaction
:(S)-5-oxo-2,5-dihydrofuran-2-acetate \rightleftharpoons 5-oxo-4,5-dihydrofuran-2-acetate
Hence, this enzyme has one substrate, (S)-5-oxo-2,5-dihydrofuran-2-acetate, and one product, 5-oxo-4,5-dihydrofuran-2-acetate.
This enzyme belongs to the family of isomerases, specifically those intramolecular oxidoreductases transposing C=C bonds. The systematic name of this enzyme class is 5-oxo-4,5-dihydrofuran-2-acetate Delta3-Delta2-isomerase. This enzyme is also called muconolactone isomerase. This enzyme participates in benzoate degradation via hydroxylation.
==Structural studies==

As of late 2007, only one structure has been solved for this class of enzymes, with the PDB accession code .

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